From Supramolecular Block Copolymers to Advanced Nano-Objects

Gohy, Jean-Francois; Lohmeijer, Bas G. G.; Schubert, Ulrich S.

Abstract:

The formation of asymmetric bis-complexes, based on terpyridine ligands and ruthenium ions, is described as a powerful tool for the self-assembly of polymer blocks end-functionalized with terpyridine units. This is illustrated in this contribution for the synthesis of amphiphilic metallo-supramolecular block copolymers, which are further used to produce aqueous micelles. Finally, the reversibility of the supramolecular bond opens new avenues for the preparation and manipulation of these nano-objects.

Year:

2003

Type of Publication:

Article

Keywords:

block copolymers; micelles; nanotechnology; supramolecular chemistry; terpyridines

Journal:

Chemistry - A European Journal

Volume:

9

Pages:

3472 – 3479