New Synthetic Strategy towards Pyridine-based Ligands for Supramolecular Chemistry utilizing 2,6 Bis(trimethyltin)pyridine as the central Building Block

Schubert, Ulrich S.; Eschbaumer, Christian

Abstract:

2,6-Bis(trimethyltin)pyridine was synthesized in high yields and multigram quantities and used for Stille-type coupling procedures to prepare 2,2¢-bipyridines, 5,5¢¢-dimethyl-2,2¢:6¢,2¢¢-terpyridine, and 4,6-bis(5¢¢-methyl-2¢¢,2¢-bipyrid-6¢-yl)-2-phenylpyrimidine.

Year:

1999

Type of Publication:

Article

Journal:

Organic Letters

Pages:

1027 – 1029