High-throughput experimentation in synthetic polymer chemistry: From RAFT and anionic polymerizations to process development

Guerrero-Sanchez, Carlos; Paulus, Renzo M.; Fijten, Martin W. M.; de la Mar, Mariska J.; Hoogenboom, Richard; Schubert, Ulrich S.

Abstract:

The application of combinatorial and high-throughput approaches in polymer research is described. An overview of the utilized synthesis robots is given, including different parallel synthesizers and a process development robot. In addition, the application of the parallel synthesis robots to reversible addition fragmentation termination (RAFT) radical polymerizations and ionic copolymerizations is overviewed. Moreover, first results concerning the process development of semi-batch free radical polymerizations are described.

Year:

2006

Type of Publication:

Article

Journal:

Applied Surface Science

Volume:

252

Pages:

2555 - 2561