Capillary Zone Electrophoresis of Iridium(III) and Ruthenium(II) Polypyridyl Complexes in Non-aqueous Solvents
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Pauw, Brian R.; Holder, Elisabeth; Marin, Veronica; Lohmeijer, Bas G. G.; Schubert, Ulrich S.
- Abstract:
- A method of non-aqueous capillary zone electrophoresis has been optimized for the characterization of five functionalized mixed-ligand iridium(III) polypyridyl complexes and four functionalized ruthenium(II) bis-terpyridine complexes. Their mobilities, the relation to their molar mass, and the capillary lifetime (measured in number of injections) have been determined.
- Year:
- 2007
- Type of Publication:
- Article
- Keywords:
- Capillary zone electrophoresis; separation; mobility; polypyridyl complexes; metal-containing polymers
- Journal:
- Analytical Letters
- Volume:
- 40
- Number:
- 1
- Pages:
- 163 - 171