Thermoreversible Ionogels with Tunable Properties via Aqeous Gelation of an Amphiphilic Quaternary Ammonium Oligoether-Based Ionic Liquid

Ribot, Josep Casamada; Guerrero-Sanchez, Carlos; Hoogenboom, Richard; Schubert, Ulrich S.

Abstract:

The gelation of the amphiphilic quaternary ammonium oligoether-based ionic liquid (AMMOENG100) with water is addressed. This approach allows the preparation of thermoreversible ionogels with high ionic conductivity (up to 60 mS cm1), remarkable mechanical properties (storage moduli above 105 Pa—a value comparable to the mechanical properties of some rubbers), and melting points in the range from 20 to 53 C. These properties can be easily tuned in a broad range by varying the water (and/or inorganic salts) concentration in the ionogels. The described method is a very convenient way to prepare ionogels because it is based on simple and inexpensive materials, namely AMMOENG100 and water (no volatile organic solvents involved). Infrared measurements suggested that the observed gelation phenomenon might occur via the formation of a hydrogen bonded network between water and the AMMOENG100 ionic liquid.

Year:

2010

Type of Publication:

Article

Journal:

Journal of Materials Chemistry

Volume:

20

Pages:

8279 - 8284