Preperation of Polyurethane Elastomers (PUEs) in a High-Throughput Workflow
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Majoros, Laszlo I.; Dekeyser, Bernard; Haucourt, Nancy; Castelein, Pieter; Paul, Johan; Kranenburg, Johannes M.; Rettler, Erik; Hoogenboom, Richard; Schubert, Ulrich S.
- Abstract:
- High-throughput experimentation (HTE) represents
a promising and versatile approach for polyurethane (PU)
research as a tool to rapidly screen and characterize a large
number of samples in an automated way. To realize a unique
HTE workflow for the research and development of PU elastomers
(PUEs), the use of parallel automated formulation and
coating platforms at Flamac were explored. To evaluate the
applicability of HTE for PUEs, four different PU systems were
investigated with different reactivities and viscosities. All prepared
PUEs were evaluated by conventional physical testing
methods measuring the E-modulus, tensile-elongation and the
hardness properties revealing similar trends as conventionally
prepared PUEs indicating the viability of the HTE approach. In
addition, the properties of the PUEs were also investigated
using downscaled microtensile bars as well as depth-sensing
indentation, again, revealing similar trends. With this proof of
principle study, we demonstrated for the first time that HTE
can also be extended to polymeric materials based on high reactive
and viscous raw materials in combination with complex
technologies. The reported results provide a basis for the use
of HTE approaches for preparing, screening and characterizing
large numbers of PUEs for R{&}D purposes.
- Year:
- 2011
- Type of Publication:
- Article
- Keywords:
- depth sensing indentation; high performance coatings; high throughput experimentation; mechanical properties; polyurethane elastomers PUEs
- Journal:
- Journal of Polymer Science: Part A: Polymer Chemistry
- Volume:
- 49
- Pages:
- 301 - 313