Tailor Made Side-Chain Functionalized Macromolecules by Combination of Controlled Radical Polymerization and Click Chemistry
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Krieg, Andreas; Becer, C. Remzi; Hoogenboom, Richard; Schubert, Ulrich S.
- Abstract:
- Reversible addition-fragmentation chain transfer polymerization of trimethylsilyl-
propargyl methacrylate (TMSPMA) was performed to obtain alkyne containing
polymers with narrow molecular weight distributions (PDIzed using the copper(I) catalyzed
alkyne-azide cycloaddition reaction to obtain well-defined glycopolymers,
grafted copolymers and anthracene-containing polymers (PDI¼1.08–1.28) that were
characterized with GPC, MALDI-TOF mass spectrometry and 1H-NMR-spectroscopy.
- Year:
- 2009
- Type of Publication:
- Article
- Journal:
- Macromolecular Symposia
- Volume:
- 275-276
- Pages:
- 73–81