Blue emitting side-chain pendant 4-hydroxy-1,3-thiazoles in polystyrenes synthesized by RAFT polymerization

Breul, Alexander; Pietsch, Christian; menzel, Roberto; Schäfer, Johann; Teichler, Anke; Hager, Martin D.; J\", ; urgen Popp, ; Dietzek, Benjamin; Beckert, Rainer; Schubert, Ulrich S.

Abstract:

Blue emitting dyes bearing a luciferin analogous chromophore were attached to a polystyrene backbone. For this purpose, 4-hydroxy-1,3-thiazoles were functionalized with a styrene unit and polymerized using the reversible addition–fragmentation chain transfer (RAFT) polymerization technique. Two different chain transfer agents were investigated and one monomer was studied in terms of its kinetic behavior. The polymerization kinetics are presented and discussed in detail, showing a controlled polymerization behavior, resulting in well-defined copolymers with polydispersity indices below 1.2. The obtained polymers were characterized by size exclusion chromatography (SEC), 1H NMR, MALDI-TOF MS and UV–vis absorption and fluorescence spectroscopy. In addition, the UV–vis absorption and emission behavior was investigated in thin films.

Year:

2012

Type of Publication:

Article

Keywords:

Blue chromophores; Donor dyes; Fluorescence; Reversible addition fragmentation chain transfer RAFT; Styrene; Thiazoles

Journal:

European Polymer Journal

Volume:

48

Pages:

1339 - 1347