Soluble PtII-Containing Polymers Based on a 2,6-Bis(1H-1,2,3-triazol-4-yl)-4-ethynylpyridine Ligand
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Schulze, Benjamin; Winter, Andreas; Friebe, Christian; Birckner, Eckhard; Schubert, Ulrich S.
- Abstract:
- A soluble PtII-acetylide polymer 6 was prepared in a supramolecular polymerization of a PtII-chloro precursor complex 5, which represents a self-complementary AB-type monomer. This new type of polymer combines the structural features of the common polyplatinynes and cationic PtII-acetylide complexes. Though the photophysical and electrochemical properties of the material still need to be advanced, a versatile and straightforward method for the preparation of soluble, cationic PtII-acetylide polymers with phosphorescent behavior is offered.
- Research areas:
- Year:
- 2017
- Type of Publication:
- Article
- Journal:
- ACS Macro Letters
- Volume:
- 6
- Pages:
- 181 - 184
- DOI:
- 10.1021/acsmacrolett.6b00936