4'-Functionalized 2,2':6',2''-Terpyridines as Building Blocks for Supramolecular Chemistry and Nanoscience
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Schubert, Ulrich S.; Eschbaumer, Christian; Hien, Oliver; Andres, Philip R.
- Abstract:
- Different mono- and bis-terpyridines were synthesized utilizing nucleophilic substitution of 4-chloro-2,2:6,2-terpyridine.
In the case of the mono-functionalized ligands, different functional groups opposite to the metal binding site could be
introduced; with the bis-functionalized ligands building blocks for metal-containing polymers with a tailored alkyl-chain length
were accessible. As examples, a functionalized terpyridine cadmium(II) complex as well as a fullerene derivative were prepared.
- Year:
- 2001
- Type of Publication:
- Article
- Journal:
- Tetrahedron Letters
- Volume:
- 42
- Pages:
- 4705 – 4707